Infrared Absorption and Laser Spectroscopy of Ho$^{3+}$ Doped K$_2$YF$_5$ Microparticles
- URL: http://arxiv.org/abs/2510.16345v1
- Date: Sat, 18 Oct 2025 04:18:06 GMT
- Title: Infrared Absorption and Laser Spectroscopy of Ho$^{3+}$ Doped K$_2$YF$_5$ Microparticles
- Authors: Pakwan Chanprakhon, Michael F. Reid, Jon-Paul R. Wells,
- Abstract summary: This optical data is used for crystal-field modelling of the electronic structure of Ho$3+$ in K$$YF$_5$ microparticles.<n>Temperature dependence of the fluorescent lifetime of the $5$F$_5$ multiplet is measured.<n> measurements of infra-red to visible upconversion in microparticles co-doped with Ho$3+$ and Yb$3+$ is reported.
- Score: 0.0
- License: http://creativecommons.org/licenses/by-nc-nd/4.0/
- Abstract: High-resolution absorption and laser spectroscopy are used to determine electronic energy levels for Ho$^{3+}$ ions in K$_2$YF$_5$ microparticles. A total of 72 crystal-field energy levels, distributed among 8 multiplets, are assigned. This optical data is used for crystal-field modelling of the electronic structure of Ho$^{3+}$ in K$_2$YF$_5$. Partially-resolved hyperfine splittings are accurately reproduced by the model. The temperature dependence of the fluorescent lifetime of the $^5$F$_5$ multiplet is measured and the temperature dependence of the non-radiative relaxation is modelled by a five-phonon process. Preliminary measurements of infra-red to visible upconversion in microparticles co-doped with Ho$^{3+}$ and Yb$^{3+}$ is reported.
Related papers
- Spectroscopy of Sm$^{3+}$ Ions in the C$_{\rm s}$ Symmetry Centres of Hydrothermally Prepared K$_2$YF$_5$ Microcrystals [0.0]
We report on the synthesis and spectroscopic characterization of Sm$3+$-doped K$$$YF$_5$ microparticles.<n>The particles were synthesized via the hydrothermal technique, yielding a particle size of approximately 20 $mu$m in length.
arXiv Detail & Related papers (2025-10-13T20:59:28Z) - Cryogenic Microwave Whispering Gallery Mode Spectroscopy of Paramagnetic Impurities in High-Purity Crystalline LiF [0.2999888908665658]
A low-noise cryogenic microwave spectroscopy experiment was performed on a high-purity lithium fluoride (LiF) crystal.<n>The spectroscopy data revealed avoided level crossing interactions in whispering gallery modes.<n>The number of hyperfine splittings observed, together with the natural abundance of ions possessing the appropriate nuclear spin values, suggest that V$2+$ and V$3+$ impurities, exhibiting orthorhombic distortion, are the most likely sources of the narrow interaction features.
arXiv Detail & Related papers (2025-05-25T14:42:02Z) - Spectroscopy and Crystal-Field Analysis of Low -Symmetry Er$^{3+}$ Centres in K$_2$YF$_5$ Microparticles [0.0]
K$$YF$_5$ crystals doped with lanthanide ions have a variety of possible optical applications.
electron-paramagnetic resonance studies have demonstrated that lanthanide ions substitute for yttrium in sites of C$_rm s$ local ambiguities.
arXiv Detail & Related papers (2024-09-24T00:23:38Z) - Precision Multi-Mode Microwave Spectroscopy of Paramagnetic and Rare-Earth Ion Spin Defects in Single Crystal Calcium Tungstate [0.0]
We present experimental observations of dilute ion spin ensemble defects in a low-loss single crystal cylindrical sample of CaWO$_4$ cooled to $30$ mK in temperature.
The resonator exhibited numerous whispering gallery modes with high $Q$-factors of up to $3times 107$, equivalent to a loss tangent of $sim 3times 10-8$.
arXiv Detail & Related papers (2023-12-08T17:41:06Z) - Optical coherence properties of Kramers' rare-earth ions at the
nanoscale for quantum applications [41.30071614056703]
Rare-earth (RE) ion doped nano-materials are promising candidates for a range of quantum technology applications.
Among RE ions, the so-called Kramers' ions possess spin transitions in the GHz range at low magnetic fields.
We measure spectroscopic properties that are of relevance to using these materials in quantum technology applications.
arXiv Detail & Related papers (2023-03-03T16:23:29Z) - Reproduction of the electronic and magnetic structure of the low
symmetry sites of Y$_{2}$SiO$_{5}$ doped with Sm$^{3+}$ via a parameterized
crystal-field model [0.0]
Parametrized crystal-field analyses are presented for both the six and seven fold coordinated, C$_1$ symmetry Sm$3+$ centers.
The resultant analyses give good approximation to the experimental energy levels and magnetic splittings, yielding crystal-field parameters consistent with the few other lanthanide ions.
arXiv Detail & Related papers (2022-06-18T01:20:58Z) - Near-monochromatic tuneable cryogenic niobium electron field emitter [48.7576911714538]
We describe electron field emission from a monocrystalline, superconducting niobium nanotip at a temperature of 5.9 K.
The emitted electron energy spectrum reveals an ultra-narrow distribution down to 16 meV.
This source will decrease the impact of lens aberration and enable new modes in low-energy electron microscopy, electron energy loss spectroscopy, and high-resolution vibrational spectroscopy.
arXiv Detail & Related papers (2022-05-11T20:46:21Z) - Rapid generation of all-optical $^{39}$K Bose-Einstein condensates using
a low-field Feshbach resonance [58.720142291102135]
We investigate the production of all-optical $39$K Bose-Einstein condensates with different scattering lengths using a Feshbach resonance near $33$ G.
We are able to produce fully condensed ensembles with $5.8times104$ atoms within $850$ ms evaporation time at a scattering length of $232.
Based on our findings we describe routes towards high-flux sources of ultra-cold potassium for inertial sensing.
arXiv Detail & Related papers (2022-01-12T16:39:32Z) - High-resolution 'magic'-field spectroscopy on trapped polyatomic
molecules [62.997667081978825]
Rapid progress in cooling and trapping of molecules has enabled first experiments on high resolution spectroscopy of trapped diatomic molecules.
Extending this work to polyatomic molecules provides unique opportunities due to more complex geometries and additional internal degrees of freedom.
arXiv Detail & Related papers (2021-10-21T15:46:17Z) - Algorithmic Ground-state Cooling of Weakly-Coupled Oscillators using
Quantum Logic [52.77024349608834]
We introduce a novel algorithmic cooling protocol for transferring phonons from poorly- to efficiently-cooled modes.
We demonstrate it experimentally by simultaneously bringing two motional modes of a Be$+$-Ar$13+$ mixed Coulomb crystal close to their zero-point energies.
We reach the lowest temperature reported for a highly charged ion, with a residual temperature of only $Tlesssim200mathrmmu K$ in each of the two modes.
arXiv Detail & Related papers (2021-02-24T17:46:15Z) - Electrically tuned hyperfine spectrum in neutral
Tb(II)(Cp$^{\rm{iPr5}}$)$_2$ single-molecule magnet [64.10537606150362]
Both molecular electronic and nuclear spin levels can be used as qubits.
In solid state systems with dopants, an electric field was shown to effectively change the spacing between the nuclear spin qubit levels.
This hyperfine Stark effect may be useful for applications of molecular nuclear spins for quantum computing.
arXiv Detail & Related papers (2020-07-31T01:48:57Z) - Resonant high-energy bremsstrahlung of ultrarelativistic electrons in
the field of a nucleus and a pulsed light wave [68.8204255655161]
Research investigates the resonant high-energy spontaneous bremsstrahlung of ultrarelativistic electrons with considerable energies in the field of a nucleus and a quasimonochromatic laser wave.
arXiv Detail & Related papers (2020-04-05T16:27:11Z)
This list is automatically generated from the titles and abstracts of the papers in this site.
This site does not guarantee the quality of this site (including all information) and is not responsible for any consequences.