Early Cycle Charge Trajectory Generative Prediction and Full Life Cycle Health Management of Iron-Chromium Flow Batteries Based on FlowBD-E1

• URL: http://arxiv.org/abs/2608.14637v1
• Date: Tue, 28 Jul 2026 09:02:14 GMT
• Title: Early Cycle Charge Trajectory Generative Prediction and Full Life Cycle Health Management of Iron-Chromium Flow Batteries Based on FlowBD-E1
• Abstract summary: FlowBD-E1, an early-cycle generative forecasting framework, predicts complete future charge V/I trajectories from only the first few cycles.<n>Results suggest that early-cycle trajectory generation can turn a short commissioning record into a long-horizon diagnostic signal for flow-battery management.
• Score: 3.6963089752268687
• License: http://arxiv.org/licenses/nonexclusive-distrib/1.0/
• Abstract: Long-duration stationary energy storage requires batteries whose degradation can be detected before substantial capacity loss has accumulated. Iron-chromium redox flow batteries are attractive for this role because they use abundant and low-cost active species, yet their operation is shaped by slow chromium kinetics, hydrogen evolution, membrane crossover and electrolyte imbalance. These coupled processes gradually reshape the full charge voltage/current (V/I) trajectory, but most battery prognostic studies either focus on lithium-ion cells or compress ageing into scalar capacity and state-of-health (SOH) labels. Here we study an industrial 33 kW Fe-Cr redox flow battery and introduce FlowBD-E1, an early-cycle generative forecasting framework that predicts complete future charge V/I trajectories from only the first few cycles. The model combines a multi-scale convolutional encoder, a lifecycle Transformer and an age-aware FiLM decoder, and we compare three deployment strategies: single-step latent extrapolation (SLE), recursive latent forecasting (RLF) and teacher-forced updating (TFU). Using the first 9 of 289 cycles, RLF achieved a joint V/I mean absolute percentage error (MAPE) of 0.731% over the remaining lifecycle and produced SOH estimates below 1% MAPE. Ablation and independent-sequence tests showed that the age-aware generative architecture outperformed LSTM and TCN baselines and retained sub-percent errors under industrial validation. These results suggest that early-cycle trajectory generation can turn a short commissioning record into a long-horizon diagnostic signal for flow-battery management.

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