Observation of Chemical Reactions between a Trapped Ion and Ultracold
Feshbach Dimers
- URL: http://arxiv.org/abs/2110.14475v2
- Date: Wed, 6 Apr 2022 13:30:09 GMT
- Title: Observation of Chemical Reactions between a Trapped Ion and Ultracold
Feshbach Dimers
- Authors: H. Hirzler, R.S. Lous, E. Trimby, J. P\'erez-R\'ios, A. Safavi-Naini
and R. Gerritsma
- Abstract summary: We measure chemical reactions between a single trapped $174$Yb$+$ ion immersed in an ultracold bath of $6$Li atoms.
This produces LiYb$+$ molecular ions that we detect via mass spectrometry.
- Score: 0.0
- License: http://creativecommons.org/licenses/by-nc-nd/4.0/
- Abstract: We measure chemical reactions between a single trapped $^{174}$Yb$^+$ ion
immersed in an ultracold bath of $^6$Li atoms containing trace amounts of
Li$_2$ dimers. This produces LiYb$^+$ molecular ions that we detect via mass
spectrometry. We explain the reaction rates by modelling the dimer density as a
function of the magnetic field and obtain excellent agreement when we assume
the reaction to follow the Langevin rate. Our results present a novel approach
towards the creation of cold molecular ions and point to the exploration of
ultracold chemistry in ion molecule collisions. What is more, with a detection
sensitivity below molecule densities of $10^{14}\,\mathrm{m}^{-3}$, we provide
a new method to detect low-density molecular gases.
Related papers
- Rotational excitation in sympathetic cooling of diatomic molecular ions by laser-cooled atomic ions [0.0]
We estimate rotational state changes in collisions of diatomic ions with atomic ions.
We also estimate the cooling time, considering both a single atomic ion and a Coulomb crystal of atomic ions.
arXiv Detail & Related papers (2024-10-29T18:47:09Z) - Analytical Correlation in the H$_{2}$ Molecule from the Independent Atom Ansatz [49.1574468325115]
The total energy functional correctly dissociates the H-H bond and yields absolute errors of 0.002 $rA$, 0.19 eV, and 13 cm-1$ relative to experiment at the tight binding computational cost.
The chemical bond formation is attributed to the Heitler-London resonance of quasi-orthogonal atomic states with no contributions from kinetic energy or charge accumulation in the bond.
arXiv Detail & Related papers (2024-05-20T21:21:42Z) - Excitations of N$_{2 }$ and O$_{2}$ molecules due to helium ion impact
and a polarization effect [0.0]
We present an experimental study of the dissociative excitation in the collision of helium ions with nitrogen and oxygen molecules.
The emission of excited dissociative products was detected using an improved high-resolution optical spectroscopy method.
arXiv Detail & Related papers (2023-12-27T18:42:48Z) - Observation of Rydberg blockade due to the charge-dipole interaction
between an atom and a polar molecule [52.77024349608834]
We demonstrate Rydberg blockade due to the charge-dipole interaction between a single Rb atom and a single RbCs molecule confined in optical tweezers.
Results open up the prospect of a hybrid platform where quantum information is transferred between individually trapped molecules using Rydberg atoms.
arXiv Detail & Related papers (2023-03-10T18:41:20Z) - Magnetic trapping of ultracold molecules at high density [0.0]
We report magnetic trapping of NaLi molecules in the triplet ground state at high density and ultralow temperature.
This allows studies on both atom-molecule and molecule-molecule collisions in the ultracold regime.
We demonstrate sympathetic cooling of NaLi molecules in the magnetic trap by radio frequency evaporation of co-trapped Na atoms.
arXiv Detail & Related papers (2022-11-20T23:33:26Z) - Impact of the ligand deformation on the
$\mathcal{P}$,$\mathcal{T}$-violation effects in the YbOH molecule [77.34726150561087]
The ytterbium monohydroxide is a promising molecule for a new physics searches.
We have calculated the value of $l$-doubling for the YbOH molecule with approximation of fixed O-H bond length.
arXiv Detail & Related papers (2022-08-15T08:16:19Z) - Ion-molecule reactions below 1~K: Observation of a strong enhancement of
the reaction rate of the ion-dipole reaction He$^+$+ CH$_3$F [55.41644538483948]
Reaction between He$+$ and CH$_3$F forming predominantly CH$+$ and CHF$+$.
To avoid heating of the ions by stray electric fields, the reaction was observed within the orbit of a highly excited Rydberg electron.
arXiv Detail & Related papers (2021-12-22T17:32:43Z) - High-resolution 'magic'-field spectroscopy on trapped polyatomic
molecules [62.997667081978825]
Rapid progress in cooling and trapping of molecules has enabled first experiments on high resolution spectroscopy of trapped diatomic molecules.
Extending this work to polyatomic molecules provides unique opportunities due to more complex geometries and additional internal degrees of freedom.
arXiv Detail & Related papers (2021-10-21T15:46:17Z) - Algorithmic Ground-state Cooling of Weakly-Coupled Oscillators using
Quantum Logic [52.77024349608834]
We introduce a novel algorithmic cooling protocol for transferring phonons from poorly- to efficiently-cooled modes.
We demonstrate it experimentally by simultaneously bringing two motional modes of a Be$+$-Ar$13+$ mixed Coulomb crystal close to their zero-point energies.
We reach the lowest temperature reported for a highly charged ion, with a residual temperature of only $Tlesssim200mathrmmu K$ in each of the two modes.
arXiv Detail & Related papers (2021-02-24T17:46:15Z) - Resonant dipolar collisions of ultracold molecules induced by microwave
dressing [0.0]
We demonstrate microwave dressing on ultracold, fermionic $23$Na$40$K ground-state molecules.
We observe resonant dipolar collisions with cross sections exceeding three times the $s$-wave unitarity limit.
arXiv Detail & Related papers (2020-03-05T18:57:57Z)
This list is automatically generated from the titles and abstracts of the papers in this site.
This site does not guarantee the quality of this site (including all information) and is not responsible for any consequences.