Approaching the Thermodynamic Limit of an Ideal Gas

• URL: http://arxiv.org/abs/2510.24552v1
• Date: Tue, 28 Oct 2025 15:48:25 GMT
• Title: Approaching the Thermodynamic Limit of an Ideal Gas
• Abstract summary: For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles.<n>We contrast a classical and a quantum model of particle-wall correlations within the canonical ensemble.
• Score: 0.0
• License: http://creativecommons.org/licenses/by/4.0/
• Abstract: For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles. While such correlations have a vanishing effect in the thermodynamic limit, examining them is beneficial for a sharper understanding of how the limit is attained. We contrast a classical and a quantum model of particle-wall correlations within the canonical ensemble.

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