Thickness dependent dark exciton emission in (PEA)2PbI4 nanoflake and
its brightening by in-plane magnetic field
- URL: http://arxiv.org/abs/2111.07888v2
- Date: Mon, 22 Nov 2021 11:42:28 GMT
- Title: Thickness dependent dark exciton emission in (PEA)2PbI4 nanoflake and
its brightening by in-plane magnetic field
- Abstract summary: We report the gradually brightened emission of the dark exciton (DX) in 2D halide perovskite material.
The fine splitting of all the four states are observed in static PL spectroscopy for the first time.
- Score: 15.381415050141477
- License: http://creativecommons.org/licenses/by/4.0/
- Abstract: Halide perovskite materials raised tremendous interest in recent years since
their cheap fabrication, superior performance in both solar cell and light
emitting diode (LED). Due to the existence of layered quantum well structure,
quasi two-dimensional(2D) halide perovskite has more intriguing spin related
physics than its 3D counterpart. For instance, the detection and brightening of
dark exciton (DX) in 2D halide perovskite attracts much attention since these
species can be used in opto-spintronic and quantum computing devices. Here, we
report the gradually brightened emission of the DX at 2.33 eV with the
thickness decreases in (PEA)2PbI4 single crystalline nanoflake, which hitherto
has not been reported. By coupling with in-plane (IP) magnetic field in Voigt
configuration, the DX emission can be sharply enhanced, while for the
out-of-plane (OP) magnetic field in Faraday configuration, the DX emission has
no noticeable change, which can be reconciled with the theory interpretation of
magnetic field dependent wave function mixing between the four exciton states
fi1, fi2, fi3- , fi3+. The emission of DX fi2 at 2.335 eV and the fine
splitting of all the four states are observed in static PL spectroscopy for the
first time. Our work thus clarifies the debating questions regarding to
previous research on DX behavior in 2D halide perovskite material and sheds
light on the road of realizing opto-spintronic or quantum computing devices
with these materials.
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