Cartesian operator factorization method for Hydrogen

• URL: http://arxiv.org/abs/2201.01761v1
• Date: Wed, 5 Jan 2022 18:49:37 GMT
• Title: Cartesian operator factorization method for Hydrogen
• Authors: Xinliang Lyu, Christina Daniel, and James K. Freericks
• Abstract summary: We generalize Schroedinger's factorization method for Hydrogen to a Cartesian-based factorization. We determine the eigenstates and energies, the wavefunctions in both coordinate and momentum space.
• Score: 0.0
• License: http://arxiv.org/licenses/nonexclusive-distrib/1.0/
• Abstract: We generalize Schroedinger's factorization method for Hydrogen from the conventional separation into angular and radial coordinates to a Cartesian-based factorization. Unique to this approach, is the fact that the Hamiltonian is represented as a sum over factorizations in terms of coupled operators that depend on the coordinates and momenta in each Cartesian direction. We determine the eigenstates and energies, the wavefunctions in both coordinate and momentum space, and we also illustrate how this technique can be employed to develop the conventional confluent hypergeometric equation approach. The methodology developed here could potentially be employed for other Hamiltonians that can be represented as the sum over coupled Schroedinger factorizations.

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