Illusory cracks in the second law of thermodynamics in quantum
nanoelectronics
- URL: http://arxiv.org/abs/2304.03106v1
- Date: Thu, 6 Apr 2023 14:35:23 GMT
- Title: Illusory cracks in the second law of thermodynamics in quantum
nanoelectronics
- Authors: Robert S. Whitney
- Abstract summary: This is a review of the theory of quantum thermodynamic demons.
These are quantum systems that look like they violate the laws of thermodynamics.
It concentrates on autonomous demons that can be made using nanoelectronics.
- Score: 0.0
- License: http://creativecommons.org/licenses/by-sa/4.0/
- Abstract: This is a review of the theory of quantum thermodynamic demons; these are
quantum systems that look like they violate the laws of thermodynamics, in
analogy with Maxwell's demon. It concentrates on autonomous demons that can be
made using nanoelectronics. Here ``autonomous'' means that the demon operates
without any external measurement or driving, making it possible to model their
entire thermodynamic behaviour using Schr\"odinger's equation. My main aim is
to review why cracks in the laws of thermodynamics, sometimes glimpsed in such
systems, have turned out to be illusory.
For this, I work by example, introducing the methods of quantum
thermodynamics via an old thought experiment that appears to break the second
law. This thought experiment is usually known as Smoluchowski's trapdoor,
although it was first proposed by Maxwell. Smoluchowski showed that the
trapdoor's thermal motion complicates its dynamics, but I argue that he did not
show that it must obey the second law. This question is now of practical
relevance, because a nanoelectronic version of the trapdoor can be made with
quantum dots. The methods presented here show that such a quantum trapdoor
obeys the laws of thermodynamics.
This reviews then addresses other types of autonomous demon that
superficially appear to break the laws of thermodynamics, but which do not.
These include an experimental demonstration of a Maxwell demon, and a kind of
demon that exploit non-equilibrium resources (the N-demon). It discusses a way
of classifying different kinds of autonomous demon. It concludes by briefly
reviewing how fluctuations affect nanoelectronics, and how their role in
stochastic thermodynamics changes our view of entropy.
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