Open-system approach to nonequilibrium quantum thermodynamics at arbitrary coupling

• URL: http://arxiv.org/abs/2109.11893v3
• Date: Mon, 30 May 2022 12:27:42 GMT
• Title: Open-system approach to nonequilibrium quantum thermodynamics at arbitrary coupling
• Authors: Alessandra Colla and Heinz-Peter Breuer
• Abstract summary: We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths. Our approach is based on the exact time-local quantum master equation for the reduced open system states.
• Score: 77.34726150561087
• License: http://creativecommons.org/licenses/by-nc-sa/4.0/
• Abstract: We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open system states, and on a principle of minimal dissipation. This principle leads to a unique prescription for the decomposition of the master equation into a Hamiltonian part representing coherent time evolution and a dissipator part describing dissipation and decoherence. Employing this decomposition we demonstrate how to define work, heat, and entropy production, formulate the first and second law of thermodynamics, and establish the connection between violations of the second law and quantum non-Markovianity.

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