Optimizing CMOS-compatible, superconducting Titanium Nitride Resonators: Deposition Conditions and Structuring Processes
- URL: http://arxiv.org/abs/2603.00441v1
- Date: Sat, 28 Feb 2026 03:48:09 GMT
- Title: Optimizing CMOS-compatible, superconducting Titanium Nitride Resonators: Deposition Conditions and Structuring Processes
- Authors: Simon J. K. Lang, Alexandra Schewski, Ignaz Eisele, Johannes Weber, Carla Moran-Guizan, Zhen Lou, Moritz Singer, Benedikt Schoof, Marc Tornow, Thomas Mayer, Daniela Zahn, Rui N. Pereira, Christoph Kutter,
- Abstract summary: We report on the fabrication and characterization of superconducting coplanar waveguide (CPW) resonators based on titanium nitride (TiN) thin films deposited on 200,mm diameter Si(100) substrates.
- Score: 28.404018926483985
- License: http://arxiv.org/licenses/nonexclusive-distrib/1.0/
- Abstract: We report on the fabrication and characterization of superconducting coplanar waveguide (CPW) resonators based on titanium nitride (TiN) thin films deposited on 200\,mm diameter high-resistivity Si(100) substrates. We systematically investigate how deposition conditions, dry-etch power and in-situ resist strip temperature affect morphology, superconducting properties and dielectric losses. By tuning reactive sputtering conditions, three distinct preferred crystal orientations - (111), (200), and mixed are achieved. Our results demonstrate that all films exhibiting similar minimal two-level system (TLS) losses, with TiN111 exhibit the lowest median TLS losses $\tildeδ_\mathrm{TLS}$, and greater robustness against reoxidation. The applied structuring process, in contrast, had a far greater influence on the TLS loss than the crystal orientation of the TiN film and, consequently, the intrinsic material properties of the superconducting layer. The lowest TLS losses for all TiN depositons were achieved with a low power etch and low temperature resist strip. An additional buffered oxide etch (BOE) treatment could remove high-loss interfacial oxides at the metal-air (MA) and substrate-air (SA) interface and recover the etch-induced TLS losses. Consequently, TiN resonators exhibiting $\tildeδ_\mathrm{TLS}$ values as low as $9.67 \times 10^{-7}$ were realized. The corresponding median low-power loss, $\tildeδ_\mathrm{LP}$, amounts to $11.04 \times 10^{-7}$, which translates to an internal quality factor approaching one million. These findings highlight the critical role of process induced oxide formation at the MA and SA interfaces in limiting the performance of TiN resonators and provide a scalable, low-loss process compatible with industry-grade 200 mm CMOS qubit fabrication workflows.
Related papers
- Reducing TLS loss in tantalum CPW resonators using titanium sacrificial layers [0.0]
We demonstrate a substantial reduction in two-level sacrificial system loss in tantalum coplanar waveguide resonators fabricated on high-resistivity silicon substrates.<n>A 0.2nm titanium film, deposited atop pre-sputtered -tantalum, acts as a solid-state oxygen getter that chemically modifies the native Ta oxide at the metal-air interface.
arXiv Detail & Related papers (2026-01-22T23:45:36Z) - Improving the lifetime of aluminum-based superconducting qubits through atomic layer etching and deposition [0.11785699115424035]
We present a dry surface treatment combining atomic layer etching and deposition (ALE and ALD) to mitigate dielectric loss in superconducting quantum devices formed from aluminum thin films on silicon.<n>We measure a two-fold reduction in loss attributed to two-level system absorption in treated aluminum-based resonators and planar transmon qubits.
arXiv Detail & Related papers (2025-06-20T20:41:53Z) - Tantalum thin films sputtered on silicon and on different seed layers: material characterization and coplanar waveguide resonator performance [1.927480729357611]
Superconducting qubits are a promising platform for large-scale quantum computing.
In the past, most qubit architectures have relied on niobium (Nb) as the material of choice for the superconducting layer.
One such material is tantalum (Ta), for which high-performance qubit components have already been demonstrated.
arXiv Detail & Related papers (2024-09-09T20:03:10Z) - Enhanced Superconducting Qubit Performance Through Ammonium Fluoride Etch [29.705263765768372]
Performance of superconducting qubits is often limited by dissipation and two-level systems (TLS) losses.
Here, we explore a novel wet chemical surface treatment at the Josephson junction-substrate and the substrate-air interface.
arXiv Detail & Related papers (2024-08-05T23:25:46Z) - Improved Coherence in Optically-Defined Niobium Trilayer Junction Qubits [45.786749852292246]
Niobium offers the benefit of increased operating temperatures and frequencies for superconducting devices.
We revisit niobium trilayer junctions and fabricate all-niobium transmons using only optical lithography.
We characterize devices in the microwave domain, measuring coherence times up to $62mu$s and an average qubit quality factor above $105$.
arXiv Detail & Related papers (2023-06-09T13:26:13Z) - Van der Waals Materials for Applications in Nanophotonics [49.66467977110429]
We present an emerging class of layered van der Waals (vdW) crystals as a viable nanophotonics platform.
We extract the dielectric response of 11 mechanically exfoliated thin-film (20-200 nm) van der Waals crystals, revealing high refractive indices up to n = 5.
We fabricate nanoantennas on SiO$$ and gold utilizing the compatibility of vdW thin films with a variety of substrates.
arXiv Detail & Related papers (2022-08-12T12:57:14Z) - Precision measurement of the microwave dielectric loss of sapphire in
the quantum regime with parts-per-billion sensitivity [50.591267188664666]
Dielectric loss is known to limit state-of-the-art superconducting qubit lifetimes.
Recent experiments imply upper bounds on bulk dielectric loss tangents on the order of $100$ parts-per-billion.
We have devised a measurement method capable of separating and resolving bulk dielectric loss with a sensitivity at the level of $5$ parts per billion.
arXiv Detail & Related papers (2022-06-29T00:14:11Z) - Titanium Nitride Film on Sapphire Substrate with Low Dielectric Loss for
Superconducting Qubits [28.298796614798015]
TiN film on sapphire substrate is an ideal material system for high-coherence superconducting qubits.
We reproducibly achieve qubit lifetimes of up to 300 $mu$s and quality factors approaching 8 million.
arXiv Detail & Related papers (2022-05-07T03:04:27Z) - TOF-SIMS Analysis of Decoherence Sources in Nb Superconducting
Resonators [48.7576911714538]
Superconducting qubits have emerged as a potentially foundational platform technology.
Material quality and interfacial structures continue to curb device performance.
Two-level system defects in the thin film and adjacent regions introduce noise and dissipate electromagnetic energy.
arXiv Detail & Related papers (2021-08-30T22:22:47Z) - Oxygen Vacancies in Niobium Pentoxide as a Source of Two-Level System Losses in Superconducting Niobium [41.94295877935867]
oxygen vacancies in the niobium pentoxide drive two-level system (TLS) losses.
We identify a major source of quantum decoherence in three-dimensional superconducting radio-frequency (SRF) resonators and two-dimensional transmon qubits composed of oxidized niobium.
arXiv Detail & Related papers (2021-08-30T16:24:07Z) - Discovery of Nb hydride precipitates in superconducting qubits [37.69303106863453]
We report the first evidence of the formation of niobium hydrides within niobium films on silicon in superconducting qubits fabricated at Rigetti Computing.
High-resolution transmission electron microscopy (HRTEM) analyses are performed at room and cryogenic temperatures (106 K) on superconducting qubit niobium film areas.
Our findings highlight a new previously unknown source of decoherence in superconducting qubits, contributing to both quasi and two-level system (TLS) losses.
arXiv Detail & Related papers (2021-08-23T20:01:38Z) - Measurement of the Low-temperature Loss Tangent of High-resistivity
Silicon with a High Q-factor Superconducting Resonator [58.720142291102135]
We present the direct loss tangent measurement of a high-resist intrinsicivity (100) silicon wafer in the temperature range from 70 mK to 1 K.
The measurement was performed using a technique that takes advantage of a high quality factor superconducting niobium resonator.
arXiv Detail & Related papers (2021-08-19T20:13:07Z) - Quantum Sensors for Microscopic Tunneling Systems [58.720142291102135]
tunneling Two-Level-Systems (TLS) are important for micro-fabricated quantum devices such as superconducting qubits.
We present a method to characterize individual TLS in virtually arbitrary materials deposited as thin-films.
Our approach opens avenues for quantum material spectroscopy to investigate the structure of tunneling defects.
arXiv Detail & Related papers (2020-11-29T09:57:50Z) - Microscopic Relaxation Channels in Materials for Superconducting Qubits [76.84500123816078]
We show correlations between $T_$ and grain size, enhanced oxygen diffusion along grain boundaries, and concentration of suboxides near the surface.
Physical mechanisms connect these microscopic properties to residual surface resistance and $T_$ through losses arising from the grain boundaries and from defects in the suboxides.
This comprehensive approach to understanding qubit decoherence charts a pathway for materials-driven improvements of superconducting qubit performance.
arXiv Detail & Related papers (2020-04-06T18:01:15Z)
This list is automatically generated from the titles and abstracts of the papers in this site.
This site does not guarantee the quality of this site (including all information) and is not responsible for any consequences.