Rapid detection of soil carbonates by means of NIR spectroscopy, deep learning methods and phase quantification by powder Xray diffraction

• URL: http://arxiv.org/abs/2307.12341v1
• Date: Sun, 23 Jul 2023 14:32:07 GMT
• Title: Rapid detection of soil carbonates by means of NIR spectroscopy, deep learning methods and phase quantification by powder Xray diffraction
• Authors: Lykourgos Chiniadis, Petros Tamvakis
• Abstract summary: We propose a rapid and efficient way to predict carbonates content in soil by means of FT NIR spectroscopy and by use of deep learning methods. We exploited multiple machine learning methods, such as: 1) a Regressor and 2) a CNN and compare their performance with other traditional ML algorithms.
• Score: 0.0
• License: http://creativecommons.org/licenses/by/4.0/
• Abstract: Soil NIR spectral absorbance/reflectance libraries are utilized towards improving agricultural production and analysis of soil properties which are key prerequisite for agroecological balance and environmental sustainability. Carbonates in particular, represent a soil property which is mostly affected even by mild, let alone extreme, changes of environmental conditions during climate change. In this study we propose a rapid and efficient way to predict carbonates content in soil by means of FT NIR reflectance spectroscopy and by use of deep learning methods. We exploited multiple machine learning methods, such as: 1) a MLP Regressor and 2) a CNN and compare their performance with other traditional ML algorithms such as PLSR, Cubist and SVM on the combined dataset of two NIR spectral libraries: KSSL (USDA), a dataset of soil samples reflectance spectra collected nationwide, and LUCAS TopSoil (European Soil Library) which contains soil sample absorbance spectra from all over the European Union, and use them to predict carbonate content on never before seen soil samples. Soil samples in KSSL and in TopSoil spectral libraries were acquired in the spectral region of visNIR, however in this study, only the NIR spectral region was utilized. Quantification of carbonates by means of Xray Diffraction is in good agreement with the volumetric method and the MLP prediction. Our work contributes to rapid carbonates content prediction in soil samples in cases where: 1) no volumetric method is available and 2) only NIR spectra absorbance data are available. Up till now and to the best of our knowledge, there exists no other study, that presents a prediction model trained on such an extensive dataset with such promising results on unseen data, undoubtedly supporting the notion that deep learning models present excellent prediction tools for soil carbonates content.

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